Saturday, 4 August 2012

Atomic Structure

1.8 recall that atoms consist of a central nucleus, composed of protons and neutrons, surrounded by electrons, orbiting in shells
The centre of an atom is the nucleus, which is composed of protons and neutrons. Their masses are roughly equal and since the mass of the electron is pretty much negligible, most of the mass of an atom is in the nucleus. 

The electrons are found in a series of energy levels which you call shells at IGCSE. Each 'shell' can only hold a certain number of electrons, these shells can be thought of as getting progressively further from the nucleus. Electrons will always go into the lowest possible energy level, provided there is space. The first shell can only hold 2 electrons, then the shells after that can hold a maximum of 8. 

In a diagram, the electrons are shown on circles around the nucleus. Beware that these circles are just imaginary lines to help you understand that the electrons orbit around the nucleus, at IGCSE level you just need to accept that. 

For those moving on to higher levels of Chem, the 'truth' is different, it's actually not really possible to plot the path of an electron. For more information look at the following link, to be honest I don't really understand it myself, it's so confusing. 

Later in the course you will come across  dot-and-cross diagrams. Dots or crosses are used to represent electrons, in the above, Carbon has 4 outer shell electrons. They are drawn far apart even though you could draw them close to each other like in the first shell, this is because electrons would repel each other as they have the same negative charge. (Remember like charges repel). So only if you have more than 4 OSE, then do you draw them in pairs. Remember, draw the 4 OSE like in the diagram of carbon above, then pair up any OSE left. The following diagram might help you understand:
This way of drawing electrons is clear and makes it easy to count too. When you learn about ions, dot-and-cross diagrams are useful and they help you see how the electrons are transferred. Like in the above diagram, the Chlorine atom gains one electron (the cross) from the sodium atom to become a chloride ion (Cl-), whilst the sodium atom becomes a sodium ion (Na+). It is positive because it lost one electron, so it has one more proton than electron now. :)

1.9 recall the relative mass and relative charge of a proton, neutron and electron

Relative mass
Relative charge
1/1840 (negligible)

Extra (you don't need to know this): 
Protons and neutrons don't actually have exactly the same mass - neither of them has a mass of exactly 1 on the carbon-12 scale (the scale on which the relative masses of atoms are measured). On the carbon-12 scale, a proton has a mass of 1.0073, and a neutron a mass of 1.0087. 

1.10 understand the terms atomic number, mass number, isotopes and relative atomic mass (Ar)
Atomic number is the number of protons there are in the nucleus, it is sometimes called the proton number, though atomic number should be more accurate because atoms are electrically neutral, the number of protons and electrons are equal. (Protons have a charge of +1 whilst electrons are -1, so they cancel each other out.) So the atomic number tells you the number of protons and the number of electrons. 

Mass number is the number of protons and neutrons. It is sometimes known as the nucleon number, because protons/neutrons are nucleons. So if a question asks you for the number of neutrons in an atom, mass number - atomic number = no. of neutrons

Isotopes: these are atoms which have the same atomic number but different mass numbers, i.e. same number of protons but different number of neutrons.

The number of neutrons in an atom can vary a little. For instance, there are three kinds of carbon atoms 12C, 13C and 14C. Their number of neutrons varies but they have the same number of protons, because each element's atomic number is unique. If it has a different number of protons, it wouldn't be the same element anymore. So these atoms are isotopes of carbon. Bear in mind that the fact that they have varying numbers of neutrons makes no difference whatsoever to the chemical reactions of the carbon. Though their physical properties may vary. 

Mass number

Relative atomic mass (web definition): the ratio of the average mass per atom of the naturally occurring form of an element to one-twelfth the mass of an atom of carbon-12. Symbol Ar Abbreviation r.a.m. I find it easier to think of it as:
The number of times the mass of one atom of an element is heavier than 1/12 of the mass of a carbon-12 atom. Anyways, this number is always at the top of an element's symbol, it's always either mass number or RAM at the top, atomic number at the bottom - as shown below:
mass number is always on the top, atomic number at the bottom, don't mix them up. at least you know that the mass number is always greater than atomic number
1.11 calculate the relative atomic mass of an element from the relative abundances of its isotopes
You multiply the relative abundance of each isotope by its mass number, add these together, and divide by 100. It's easier to understand through an example, in this case I'll use chlorine, since it's pretty common.

Chlorine consists of 75% Chlorine-35 and 25% Chlorine-37. You can think of the data as 100 atoms, 75 having a mass of 35 and 25 with a mass of 37. So the calculation is:
[(75 x 35) + (25 x 37)] / 100 = 35.5
So the RAM of chlorine, or Ar(Cl) is 35. 
(There are tiny percentages of other chlorine isotopes but the two shown above are the most common, and so the rest are ignored at IGCSE level.)

The RAM of an element will be closer to the mass number of the more abundant isotope. For example, the RAM of chlorine is 35.5, which is closer to chlorine-35, because it is the more abundant isotope. Obviously 75% > 25%!.

1.12 understand that the Periodic Table is an arrangement of elements in order of atomic number
The number of protons in the element's atom increases across the Periodic Table as you've probably noticed in yours.

1.13 deduce the electronic configurations of the first twenty elements from their positions in the Periodic Table
To work out the electronic arrangement of an atom:

  • Look up the atomic number in the Periodic Table - making sure that you choose the right number if two numbers are given. The atomic number will always be the smaller one and tends to be below the symbol.
  • This tells you the number of protons, and hence the number of electrons.
  • Arrange the electrons in levels, always filling up an inner level before you go to an outer one. 
e.g. to find the electronic arrangement in oxygen
  • the Periodic Table gives you the atomic number of 8.
  • Therefore there are 8 protons and 8 electrons.
  • The arrangement of the electrons will be 2,6. (First shell only holds 2 electrons, then there's 6 left which occupy the second shell.)

1.14 deduce the number of outer electrons in a main group element from its position in the Periodic Table
If you look at the patterns in the table:
  • The number of electrons in the outer level is the same as the group number. (Except with helium which has only 2 electrons. The noble gases are also usually called group 0 - not group 8.) This pattern extends throughout the Periodic Table for the main groups (i.e. not including the transition elements). 
  • So if you know that barium is in group 2, it has 2 outer shell electrons (btw, outer shell electrons which I will abbreviate to OSE are also known as valence electrons); iodine is in group 7, so it has 7 OSE, lead is in group 4, so surprise surprise, it has 4 OSE. 
  • Noble gases have full outer shells. Thus they are unreactive. More on them in this post:

Friday, 3 August 2012

More on Electrolysis

Note: This post is mainly for Single Science although it could be good background information for Double Award anyway. :)

SS 1.53 describe simple experiments for the electrolysis, using inert electrodes, of aqueous solutions of sodium chloride, copper (II) sulfate and dilute sulfuric acid and predict the products

So, electrolysis can be used to decompose molten compounds as described in an earlier post on Electrolysis: 

However, for Single Science, you also need to know about electrolysis of compounds in aqueous solutions. Predicting the reactions and working out the products for aqueous solutions are less straightforward than for molten compounds. 

An aqueous solution of a compound is a mixture of two electrolytes, it's a compound dissolved in water really (so water is the solvent). For example, an aqueous solution of copper (II) sulphate contains two electrolytes: copper (II) sulphate and water. It therefore contains copper (II) sulphate ions (Cu2+) and sulphate ions (SO42-), and also small amounts of hydrogen ions (H+) and hydroxide ions (OH-) from the dissociation of water molecules.
H2O (l) à H+(aq) + OH-(aq)

These ions compete with the ions from copper (II) sulphate for discharge at the electrodes. 

In general, when an aqueous solution of an ionic compound is electrolysed, a metal or hydrogen is produced at the cathode. At the anode, a non-metal, for example oxygen or a halogen, is given off. 

Let's see if this is the case in the electrolysis of dilute sodium chloride solution. 

Electrolysis of Dilute Sodium Chloride Solution
Note: There is a difference in the products between the electrolysis of dilute sodium chloride solution and concentrated sodium chloride solution. I will elaborate later.

An aqueous solution of sodium chloride contains four different types of ions. They are
  • Ions from sodium chloride – Na+ (aq) and Cl- (aq)
  • Ions from water – H+ (aq) and OH- (aq)

When dilute sodium chloride solution is electrolysed using inert electrodes, the Naand Hions are attracted to the cathode. The Cland OHions are attracted to the anode. 

At the cathode: 
The Hand Na+ ions are attracted to the platinum cathode. Hions gains electrons from the cathode to form hydrogen gas. (The hydrogen ions accept electrons more readily than the sodium ions. As a result, Hions are discharged as hydrogen gas, which bubbles off. I will explain why Hions are preferentially discharged later.)
2H+(aq) + 2e- à H2(g)
Na+ ions remain in solution. 

At the anode:
OH- and Clare attracted to the platinum anode. OHions give up electrons to the anode to form water and oxygen gas. 
4OH-(aq) à 2H2O(l) + O2(g) + 4e-
Clions remain in solution. 

The overall reaction is: 
  2H2O(l)   à 2H2(g) + O2(g)

Since water is being removed (by decomposition into hydrogen and oxygen), the concentration of sodium chloride solution increases gradually. The overall reaction shows that the electrolysis of dilute sodium chloride solution is equivalent to the electrolysis of water.

Another important thing to note is that twice as much hydrogen is produced as oxygen. This is because for every 4 electrons that flows around the circuit, you would get one molecule of oxygen. But four electrons would produce 2 molecules of hydrogen. Hence in a diagram, you would see the volume of hydrogen produced is twice that of oxygen. Refer to the equations above and note the number of electrons involved to help you understand. 

This diagram is just to illustrate how twice as much hydrogen gas is produced. 

Electrolysis of Concentrated Sodium Chloride Solution
The only difference is that at the anode, Cl-  ions are more numerous than OHions. Consequently, Clions are discharged as chlorine gas, which bubbles off. 

2Cl- (aq) à Cl2(g) + 2e-
The OHions remain in solution.   

One volume of hydrogen gas is given off at the cathode and one volume of chlorine gas is produced at the anode. The resulting solution becomes alkaline because there are more OHthan Hions left in the solution.    

Compare the electrolysis of molten sodium chloride, dilute sodium chloride solution and concentrated sodium chloride solution:

Molten sodium chloride:
  • Cathode: Na+ ions discharged
  • Anode: Cl- discharged
Dilute NaCl solution: 
  • Cathode: H+ ions discharged
  • Anode: OH- discharged

Concentrated NaCl solution:
  • Cathode: H+ discharged
  • Anode: Cl- discharged
So you can see that Naand Clions are not always discharged even though in all 3 of the above, the electrolytes contained these ions. For example in the electrolysis of dilute NaCl solution, Hare discharged in preference to Naions. OH- ions are discharged in preference to Clions. Before I talk about the electrolysis of copper(II) sulfate and dilute sulfuric acid, I will discuss why one type of cation (or anion) in the electrolyte is more readily discharged than another type. If you already know this, just scroll right down. :)

Note: Most of the following is taken from a G.C.E. 'O' Level textbook, but I find it useful. :) 
Reactivity Series and Selective Discharge of Ions
In electrolysis, when more than one type of cation or anion is present in a solution, only one cation and one anion are preferentially discharged. This is known as the selective discharge of ions. 

How do you predict which ions are discharged in the electrolysis of a compound in aqueous solution?
If inert electrodes are used during electrolysis, the ions discharged and hence the products formed depend on three factors:
  1. The position of the metal (producing the cation) in the reactivity series. 
  2. The relative ease of discharge of an anion. 
  3. The concentration of the anion in the electrolyte. 
The ease of discharge of cations and anions during electrolysis is shown below.


NB: Ease of discharge increases as you go down the table
Potassium ion, K+
Chloride ion, Cl-
Sodium ion, Na+
Bromide ion, Br-
Calcium ion, Ca2+
Iodide ion, I-
Magnesium ion, Mg2+
Hydroxide ion, OH-
Zinc ion, Zn2+

Note: sulphate ions (SO42-) and nitrate ions (NO3-) will not be discharged during electrolysis.
Iron ion, Fe2+
Lead ion, Pb2+
Hydrogen ion, H+
Copper ion, Cu2+
Silver ion, Ag+

Selective discharge of cations during electrolysis
The cations of an element lower in the reactivity series are discharged at the cathode in preference to cations above it in the solution. This is because cations of a less reactive element accept electrons more readily. For example, if a solution containing Naand Hions is electrolysed,  Hions are discharged in preference to Naions. The more reactive the metal, the more stable its compound. They have lost a lot of energy and have lost electrons to form stable cations, so cations lower down the reactivity series are more readily discharged.

Selective discharge of anions during electrolysis
Sulphate (SO42-) and nitrate (NO3-) ions remain in the solution and are not discharged during electrolysis. If a solution containing SO42-NO3and hydroxide (OH-) ions is electrolysed, the OHions will be discharged in preference to SO42- and NO3ions. The OHions give up electrons most readily during electrolysis to form water and oxygen.
4OH- (aq) à 2H2O (l) + O2 (g) + 4e-  

Effect of concentration on selective discharge of anions
An increase in the concentration of an anion tends to promote its discharge. For example, in the electrolysis of concentrated sodium chloride solution, two types of ions are attracted to the anode: Cland OHions. According to their relative ease of discharge, OHions should be discharged preferentially. However, in concentrated sodium chloride solution,  Clions are far more numerous than OHions and so are discharged at the anode instead. 

2Cl- (aq) à Cl2 (g) + 2e-

What are the general rules for predicting selective discharge?
The following rules can be applied when predicting the products of electrolysis of any aqueous solution (using inert electrodes):

Rule 1
Identify the cations and anions in the electrolysis. Remember that an aqueous solution also contains H+ and OH- ions from the dissociation of water molecules.
Rule 2
At the anode, the product of electrolysis is always oxygen unless the electrolyte contains a high concentration of the anions, Cl-, Br­- or I- ions.
Rule 3
At the cathode, reactive metals such as sodium and potassium are never produced during electrolysis of the aqueous solution. If the cations come from a metal above hydrogen in the reactivity series, then hydrogen will be liberated (liberate=release). If the cations come from a metal below hydrogen, then the metal itself will be deposited.
Rule 4
Identify the cations and anions that remain in the solution after electrolysis. They form the product remaining in solution. Summarise the reactions.

For example, in the electrolysis of dilute sodium chloride solution, Na+ and Cl- ions remain in solution after H+ and OH- ions have been discharged. Hence the solution of sodium chloride becomes more concentrated after electrolysis.

Electrolysis of Copper (II) sulphate solution
Copper (II) sulphate solution can be electrolysed using inert platinum electrodes. (Sometimes inert carbon electrodes in the form of graphite are used.)

During electrolysis, the cathode is coated with a layer of reddish-brown solid copper. The blue colour of the solution fades gradually as more copper is deposited. The resulting electrolyte also becomes increasingly acidic.

An aqueous solution of copper (II) sulphate contains four types of ions:

  • Ions from copper (II) sulphate: Cu2+ and SO42-
  • Ions from water: Hand OH-

At the anode:
OHions and SO42- ions are attracted to the anode. OHions give up electrons more readily than SO42- ions. Consequently, OHions are preferentially discharged to give oxygen gas.

4OH- (aq) à 2H2O (l) + O2 (g) + 4e-

The SO4ions remain in solution. 

At the cathode:
Hions and Cu2+ ions are attracted to the cathode. Copper is lower than hydrogen in the reactivity series. Cu2+ ions accept electrons more readily than Hions. As a result, Cu2+ ions are preferentially discharged as copper metal (atoms). 
Cu2+ (aq) + 2e- à Cu (s)
The Hions remain in solution. 

When aqueous copper (II) sulphate is electrolysed using platinum electrodes, copper metal is deposited at the cathode and oxygen gas is given off at the anode. The overall reaction is:
2CuSO4 (aq) + 2H2O (l) à 2Cu (s) + O2 (g) + 2H2SO4 (aq)

Electrolysis of dilute sulfuric acid solution
Inert carbon or platinum electrodes are used.
At the cathode:
In this case, the only positive ions arrive at the cathode are the hydrogen ions from the acid and the water. (Adding acid to water forces it to split up/hydrolyse.) These are discharged to give hydrogen gas.

2H+ (aq) + 2e- à H2 (g)

At the anode:
At the anode, SO42- ions  and OHions (from the water) accumulate. OHions are discharged to give O2 gas. 
4OH- (aq) à 2H2O (l) + O2 (g) + 4e-

The amount of hydrogen produced is twice that of oxygen. Just like in the electrolysis of dilute sodium chloride solution.  For every 4 e- that flows around the circuit, you would get one molecule of O2 . But four electrons would produce 2 molecules of H2

Tuesday, 12 June 2012

Ionic Compounds

Note: Updated as of 2/1/13, and this blog is no longer being updated because I'm done with IGCSEs and am doing IB, which is seriously hectic. I apologise that this blog is not totally complete but it's all I have and I'm sorry. 

f) Ionic compounds

1.27 describe the formation of ions by the gain or loss of electrons

Ions are atoms or molecules with an electric charge due to the gain or loss of electrons. If electrons are lost, the ion has a positive charge. Metals tend to do this, so they form cations (positive ions), so normally elements from group 1-3 will form cations.

If electrons are gained, the ion has a negative charge. Non-metals tend to do this, and they form anions (A-Negative-ION - ANION). So elements from group 5-7 will form anions. Group 0/8 are the noble gases and are inert + unreactive, so they do not form ions.

1.28 understand oxidation as the loss of electrons and reduction as the gain of electrons

OILRIG -  Oxidation Is Lost, Reduction Is Gain

1.29 recall the charges of common ions in this specification

Positive ions/Cations
Negative ions/Anions
Name of ion
Name of ion
Copper (I)
Copper (II)
Iron (II)
Lead (II)
Nickel (II)
Iron (III)

1.30 deduce the charge of an ion from the electronic configuration of the atom from which the ion is formed

So if the electronic configuration is 2.8.1, you can see that the atom has one outer shell electron only. And so it only needs to lost that to have a full outer shell. So its ion would have a positive 1 (1+) charge, as the electronic configuration would be 2.8. Basically, if there are less outer shell electrons to lose to have a full outer shell, then the charge will be positive. (Here, it is easier to lose than gain, because the ion would have to gain SEVEN electrons to have a full outer shell!)

Another example, if the electronic configuration is 2.8.7, then the atom only needs to gain 1 outer shell electron to have a full outer shell. So the ion formed would have the electronic configuration of 2.8.8, and so the charge would be negative 1 (you’re gaining one electron, which has a negative charge (1-) ). Thus if it is easier to gain electrons, (it is here, rather than losing 7 outer shell electrons), then the charge will be negative.

Here, the Sodium (Na) has lost one electron. It doesn't have equal numbers of protons and electrons anymore; it has one less electron than protons (or you can think of it as one more proton than electrons), so it has a 1+ charge. 

The chlorine, on the other hand, has gained one electron. So it has one more electron than proton, thus it has a negative 1 charge (1-). The formula for sodium chloride is NaCl. 

The magnesium atom loses 2 electrons to an oxygen atom, and they both have full outer shells now. It is common that ions form noble gas structures like this to become more stable and unreactive like the group 0/8 elements. 

The magnesium oxide is held together by very strong attractions between the ions. The ionic bonding is stronger here than in sodium chloride as this time you have 2+ ions attracting 2- ions. The greater the charge, the greater the attraction.

The formula for magnesium oxide is MgO.

1.31 explain, using dot and cross diagrams, the formation of ionic compounds by electron transfer, limited to combinations of elements from Groups 1, 2, 3 and 5, 6, 7

This is a common example, it doesn't matter which element has dots/crosses for their electrons,  the important thing is to make it clear that the electrons are transferred from one atom to another to make 2 ions. The one losing an electron here is sodium, so it becomes a positive ion called a cation, and the chlorine atom gains an electron and becomes a chloride ion (an anion).

Diagram of bonding in magnesium oxide. A magnesium ion (2,8)2+ gives two electrons to an oxide ion (2,8)2-. Both ions have full highest energy levels
Magnesium oxide: MgO
Even though only one magnesium ion and one oxide ion is shown, the actual equation is:
2Mg + Oà 2MgO
(remember that oxygen is diatomic)

Diagram of bonding in calcium chloride. A calcium ion (2,8,8)2+ gives one electron to a chloride ion (2,8,8)- and another electron to another chloride ion (2,8,8)-. All three ions have full highest energy levels
Calcium chloride: CaCl2
However, here you have to show 2 chloride ions because calcium loses 2 electrons, and 2 chlorine atoms gain an electron each to form 2 chloride ions.

1.32 understand ionic bonding as a strong electrostatic attraction between oppositely charged ions

1.33 understand that ionic compounds have high melting and boiling points because of strong electrostatic forces between oppositely charged ions
The strong electrostatic forces between oppositely charged ions are ionic bonds as mentioned in the previous spec point. And these require a lot of energy to break, hence high melting/boiling points. 

Wednesday, 6 June 2012

Hydrogen and water

Note: I'm adding Labels at the end of posts so that when you click on them, it will show ALL the posts in that section related to it. This will make this blog easier to use, as I don't post in a specific order, rather I answer or post according to what people needed. Hope this helps and please feedback. :) 

Section 2: Chemistry of the Elements; part e) Hydrogen and water

2.26 describe the reactions of dilute hydrochloric and dilute sulfuric acids with magnesium, aluminium, zinc and iron

Metals above hydrogen in the reactivity series will react with acids to form a salt (e.g. magnesium sulfate or zinc chloride) and hydrogen. The metals are 'displacing' hydrogen. The higher the metal in the series, the more violent the reaction. (This is why if you put copper in acids, you won't see a reaction, as it is below hydrogen in the reactivity series. However, it does react with concentrated nitric acid but we're not concerned with that now.)

Metal + dilute hydrochloric acid à metal chloride + hydrogen
Metal + dilute sulfuric acid à metal sulfate + hydrogen

Magnesium reacts vigorously with cold dilute acids, and the mixture becomes very warm as heat is produced. There is rapid fizzing (effervescence) and a colourless gas is evolved, which pops with a lighted splint (the test for hydrogen). The magnesium gradually disappears and a colourless solution of magnesium sulfate or chloride is formed. 
--The reactions between magnesium and hydrochloric acid or sulfuric acid are similar because it is reacting with the hydrogen ions. All acids in solutions have hydrogen ions. Although hydrochloric acid has chloride ions, and sulfuric acid has sulfate ions, these are spectator ions. They do not participate in the reaction and are unchanged by it. 

You can rewrite the equations as ionic equations. In the case of hydrochloric acid:
Mg (s) + 2H+ (aq) + 2Cl- (aq) à Mg2+ (aq) + 2Cl- (aq) + H2 (g)

You can see that the chloride ions weren’t changed by the reaction. It is a spectator ion, so we leave it out of the ionic equation. Leaving out the spectator ions produces the ionic equation:
Mg(s) + 2H+ (aq) à Mg2+ (aq) + H2 (g)

Repeating this with sulfuric acid:
Mg (s) + 2H+ (aq) + SO42- (aq) à Mg2+ (aq) + SO42- (aq) + H2 (g)

Again, leaving out the spectator ion which is the sulfate ion in this case.
Mg(s) + 2H+ (aq) à Mg2+ (aq) + H2 (g)

So the reactions look the same because they are the same. All acids in solution contain hydrogen ions. That means that magnesium will react with any simple dilute acid in the same way. 

Aluminium is slow to start reacting, but after warming it reacts very vigorously. There is a very thin, but very strong, layer of aluminium oxide on the surface of the aluminium, which stops the acid from getting to it. On heating, the acid removes this layer, and the aluminium can show its true reactivity. With dilute hydrochloric acid:

2Al (s) + 6HCl (aq) à 2AlCl3 (aq) + 3H2 (g)

Zinc and Iron
Zinc and iron react slowly in the cold, but more rapidly on heating. Their reactions are less vigorous than that of aluminium, and iron less than zinc of course, as it is below zinc in the reactivity series. Zinc forms zinc chloride or sulfate and hydrogen. The iron forms iron (II) sulfate or iron (II) chloride and hydrogen. For example:

Zn (s) + H2SO4 (aq) à ZnSO4 (aq) + H2 (g)
Fe (s) + 2HCl (aq) à FeCl2 (aq) + H2 (g)

2.27 describe the combustion of hydrogen

Hydrogen reacts violently with oxygen in the presence of a flame to give water. It could explode if there was a lot of hydrogen. But a lighted splint placed at the mouth of a test tube of hydrogen will just give a squeaky pop as the hydrogen reacts with oxygen in the air. The lighted splint and a squeaky pop heard is the test for hydrogen. 

2.28 describe the use of anhydrous copper (II) sulfate in the chemical test for water

Anhydrous copper (II) sulfate is white, anhydrous being without water, it is dry (an--without, hydrous--related to water). Whereas hydrated copper (II) sulfate crystals are bright blue, the water is what gives it the colour, and is part of the structure. To show that the water is part of the structure, there is a '.' [dot] in the formula: 
^You see the dot in the middle? That shows the water is part of the copper sulfate crystal structure. 

So that is a chemical test for water, just add it to anhydrous copper (II) sulfate and watch it turn blue!

Adding water to anhydrous copper sulphate

2.29 describe a physical test to show whether water is pure

Heat the water and use a thermometer to check if it boils at exactly 100°C. Pure water boils at exactly 100°C. Or you can cool it until it freezes, it should freeze at exactly 0°C. My teacher said it's safer to state both, as pure water is the only substance that has these specific boiling and freezing points, whereas another substance might boil/freeze at either temperature. 

Hope this helped!